As a photography expert, I would recommend capturing photos of the newlyweds together during the golden hour, which occurs during the first and last hour of sunlight in the day. This time of day provides a soft, warm light that is flattering and creates a romantic and dreamy atmosphere for photos.
During the golden hour, the light is not harsh and creates long, soft shadows, making it ideal for creating stunning and visually appealing photographs. The warm, golden tones of the light can also enhance the mood and emotion captured in the images, adding a magical touch to the newlyweds' photos.
Alternatively, sunset also provides a beautiful and dramatic backdrop for photos of the newlyweds together. The rich, warm hues of the setting sun can create a breathtaking and unforgettable backdrop for capturing intimate and romantic moments between the newlyweds.
Ultimately, the best time to take photos of the newlyweds together will depend on the specific aesthetic and mood that the couple desires for their wedding photos. However, both the golden hour and sunset offer unique and stunning lighting conditions that can elevate the quality of the photos and create beautiful memories for the newlyweds to cherish for years to come.